配位化学课程中研究型教学模式探讨

In this paper, the implementation of research-oriented teaching mode in coordination chemistry was introduced, including the strategies, main contents and evaluation.     

Simulation of beam gas coulomb scattering in HALS

In conventional research on beam gas coulomb scattering(BGCS), only the related beam lifetime using the analytical method is studied. In this paper, using the particle-in-cell Monte Carlo collisions(PIC-MCC) method,we not only simulated the beam lifetime but also explored the effect of BGCS on the beam distribution. In order to better estimate the effect on particle distribution, we study the ultra-low emittance electron beam. Here we choose the He Fei Advanced Light Source. By counting the lost particles in a certain time, the corresponding beam lifetime we simulated is 4.8482 h/13.8492 h in x/y, which is very close to the theoretic value(5.0555 h /13.7024 h in x/y).By counting the lost particles relative to the collided particles, the simulated value of the loss probability of collided particles is 1.3431e-04, which is also very close to the theoretical value(1.3824e-04). Besides, the simulation shows there is a tail in the transverse distribution due to the BGCS. The close match of the simulation with the theoretic value in beam lifetime and loss probability indicates our simulation is reliable.     

拉普拉斯变换微分性质的若干应用

给出拉普拉斯变换微分性质在求解拉普拉斯变换和拉普拉斯逆变换时的三个应用,并分别给出相应算例.     

高维数据均值的统计监测

本文,我们结合统计过程控制方法,使用一种新的统计量用于在样本数量不充足的情况下监测高维数据。统计量利用样本协方差规范化技术避免协方差矩阵的奇异性,同时采用软阈值技术来挑选多维数据中重要的维度进行监测以减少监测噪音。本文在提出统计量后用matlab随机产生各种维度的高维数据样本进行仿真分析,并将该统计量与基于Hotelling T~2并采取广义逆矩阵的统计量进行比较。结果表明,本文使用的统计量的监测效果优于采取广义逆矩阵的方法。本文提出的方法可以应用于多指标产品生产的快速异常检测,特别是难以得到大量检测数据的产品,如检测需要破坏产品本身或者检测成本太高的产品。     

不同变质程度煤的高分辨率透射电镜分析

利用高分辨率透射电子显微镜(HRTEM)分析了三种不同变质程度煤样的结构特征。基于傅里叶-反傅里叶变换方法,并结合Matlab、Arcgis和Auto CAD软件,通过图像分析技术,获得了HRTEM照片的晶格条纹参数。结果表明,三种煤样的晶格条纹呈现不同特征,按条纹长度分别归属于1×1-8×8共计八个类型。以3×3为临界点,在1×1和2×2中,ML-8中芳香层片的比例高于DP-4和XM-3;在3×3-8×8中,ML-8中芳香层片的比例低于DP-4和XM-3。对比HRTEM和XRD参数d002发现,随着镜质组反射率的增加d002都呈现递减趋势。     

Mechanism of Insertion Reactions between Silylenoid H2SiLiF and GeH3R (R =F,OH, NH2): a Theoretical Study

Theoretical investigations on the insertion reaction mechanisms of three- membered-ring silylenoid H2 Si Li F with GeH 3R(R = F, OH, NH2) have been systematically carried out by combined density functional theory(DFT) and ab initio quantum chemical calculations. The geometries of all stationary points for these reactions were optimized using the B3 LYP method and then the QCISD method was used to calculate the single-point energies. The calculated results indicate that, there are one precursor complex(Q), one transition state(TS), and one intermediate(IM) which connect the reactants and the products along the potential energy surface. The insertion reactions of three-membered-ring silylenoid with Ge H3 R proceed in a concerted manner, forming H2RSi-Ge H3 and Li F. The calculated potential energy barriers of the three reactions are 29.17, 30.90, and 54.07 k J/mol, and the reaction energies for the three reactions are –127.05, –116.91, and –103.31 k J/mol, respectively. The insertion reactions in solvents are similar to those in vacuum. Under the same situation, the insertion reactions should occur easily in the following order: GeH 3-F GeH 3-OH GeH 3-NH2. The elucidations of the mechanism of these insertion reactions provided a new mode of silicon-germanium bond formation.     

红外动态场景生成装置空间分辨率的测试

建立了一套基于刀口灰度图红外探测的实验装置,对红外场景生成器的空间分辨率进行了测试。首先通过被测红外场景生成器产生带有刀口标志的红外图像,然后利用红外热像仪采集红外场景生成器所成的红外图像,通过对采集到的红外热图的数据处理,实现了对红外场景生成器空间分辨率的测量。测得的红外场景生成器的空间分辨率为5lp/mm,标准误差为0.04。     

一类级数求和的推广

借助收敛级数的简单运算,对一类简单级数及和数进行四种形式的推广.     

贝叶斯公式及其应用的教学研究

通过贴近生活的例子,引入贝叶斯公式,然后,介绍信用问题和在生产中的索赔问题介绍贝叶斯公式的实际应用,以使在教学中能帮助学生更深入地理解该公式.     

Research and Evaluation on Wear in Power-Shift Steering Transmission Through Oil Spectral Analysis with RKPCA Method

The most common methodology used in element concentration measurement and analyzing of wear particles is Atomic emission (AE) spectroscopy .The present paper presents an evaluation method on wear in po...